The black in this image has a much darker value than the light purples comprising most of the image, and the white of the characters' skin is a relatively lighter value. The lighter values draw attention to the characters' faces so they are easily distinguishable, while the black aura around the girl emphasizes her entire form.
Art and characters by Andrew Hussie from his comic Homestuck.
Homestuck can be found at http://www.mspaintadventures.com.
This specific panel is here: http://www.mspaintadventures.com/?s=6&p=004885
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